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Cooking in oil that has been used a long time is unhealthy, due to the
amount of free fatty acids that build up in the oil. The process of making biodiesel removes these free fatty acids, and converts them to a form that can be removed by washing the oil. Washed biodiesel has no free methanol, near zero FFA, and no NaoH. Can you then, instead of putting the biodiesel in a vehicle, simply replace it back in the deep fryer, and cook with it? |
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Ian Stirling wrote:
Cooking in oil that has been used a long time is unhealthy, due to the amount of free fatty acids that build up in the oil. The process of making biodiesel removes these free fatty acids, and converts them to a form that can be removed by washing the oil. Washed biodiesel has no free methanol, near zero FFA, and no NaoH. Can you then, instead of putting the biodiesel in a vehicle, simply replace it back in the deep fryer, and cook with it? I believe the flash point is way too low. I also dunno what the stuff tastes like. Bob |
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Ian Stirling schrieb:
Cooking in oil that has been used a long time is unhealthy, due to the amount of free fatty acids that build up in the oil. Researchers from the University of Hohenheim (Germany) have recently developed a stove (named Protos) that runs on vegetable oil. If I understand the article correctly, the secret is a tube that vaporized the oil before it is burned. http://www.spiegel.de/wissenschaft/m...413807,00.html http://www.uni-hohenheim.de/i3v/00217110/01525041.htm Goran Jovanovic from the Oregon State University invented a tiny reactor ("about the size of a credit card") that turns vegetable oil into biodiesel. http://www.forbes.com/work/feeds/ap/...ap2681244.html http://www.mccookgazette.com/story/1152821.html Regards, Joachim |
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In article ,
zxcvbob wrote: Can you then, instead of putting the biodiesel in a vehicle, simply replace it back in the deep fryer, and cook with it? I believe the flash point is way too low. I also dunno what the stuff tastes like. The flash point is somewhere between 210 and 570 degrees F (100-300 degrees C), depending on the organic source of the oil and the purity of the refined fuel. I've heard that it tastes awful. But at least it's non-toxic! sd |
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Ian Stirling wrote: Cooking in oil that has been used a long time is unhealthy, due to the amount of free fatty acids that build up in the oil. The process of making biodiesel removes these free fatty acids, and converts them to a form that can be removed by washing the oil. Washed biodiesel has no free methanol, near zero FFA, and no NaoH. Can you then, instead of putting the biodiesel in a vehicle, simply replace it back in the deep fryer, and cook with it? I'd be most concerned with the methanol group coming off during metabolism. It's a CH3-COO-R, right? It might cause some damage. Biodiesel is also a great solvent. (I used some to remove marker stains.) No telling what that great solvent will do to the cells lining your mouth and esophagus... Biodiesel also smells pretty funny - not at all like vegetable oil. (At least, the stuff that I make... ![]() Oh, and it's VERY flammable. Much, much, much more so than vegetable oil. |
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zxcvbob wrote: Ian Stirling wrote: Cooking in oil that has been used a long time is unhealthy, due to the amount of free fatty acids that build up in the oil. The process of making biodiesel removes these free fatty acids, and converts them to a form that can be removed by washing the oil. Washed biodiesel has no free methanol, near zero FFA, and no NaoH. Can you then, instead of putting the biodiesel in a vehicle, simply replace it back in the deep fryer, and cook with it? I believe the flash point is way too low. I also dunno what the stuff tastes like. Bob Some time ago, during a backpacking trip, my dinner bowl became contaminated by the nonvolatile residue left behind after some spilled cooking fuel (white gas?) evaporated away. It tasted like soap, even at very low concentration. I can't imagine how horrible food would taste if it had been fryed in biodiesel. Dave |
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In sci.chem beav wrote:
On 23 May 2006 22:05:24 -0700, wrote: Ian Stirling wrote: Cooking in oil that has been used a long time is unhealthy, due to the amount of free fatty acids that build up in the oil. The process of making biodiesel removes these free fatty acids, and converts them to a form that can be removed by washing the oil. Washed biodiesel has no free methanol, near zero FFA, and no NaoH. Can you then, instead of putting the biodiesel in a vehicle, simply replace it back in the deep fryer, and cook with it? snip Biodiesel also smells pretty funny - not at all like vegetable oil. (At least, the stuff that I make... ![]() Oh, and it's VERY flammable. Much, much, much more so than vegetable oil. of course its different. its the methyl ester of some single straight chain alkane, rather than the glycerine ester of three straight chain alkanes. consider methyl decanoate versus tridecanoic glycerolate. (my apologies to UIPAC). considering taste? i'd go for the TDG as the tasty one... Thanks all - somehow I'd become confused on the chemistry, and thought that the methanol was merely a sort-of-catalyst, that ended up contaminating the drained off glycerine, and was not present in the product. Though I note that ethanol can be used in place of it - with much nastier process control and conditions though. May be a bonus in some outlets if it is metabolised ![]() |
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Ian Stirling wrote:
In sci.chem beav wrote: On 23 May 2006 22:05:24 -0700, wrote: Ian Stirling wrote: Cooking in oil that has been used a long time is unhealthy, due to the amount of free fatty acids that build up in the oil. The process of making biodiesel removes these free fatty acids, and converts them to a form that can be removed by washing the oil. Washed biodiesel has no free methanol, near zero FFA, and no NaoH. Can you then, instead of putting the biodiesel in a vehicle, simply replace it back in the deep fryer, and cook with it? snip Biodiesel also smells pretty funny - not at all like vegetable oil. (At least, the stuff that I make... ![]() Oh, and it's VERY flammable. Much, much, much more so than vegetable oil. of course its different. its the methyl ester of some single straight chain alkane, rather than the glycerine ester of three straight chain alkanes. consider methyl decanoate versus tridecanoic glycerolate. (my apologies to UIPAC). considering taste? i'd go for the TDG as the tasty one... Thanks all - somehow I'd become confused on the chemistry, and thought that the methanol was merely a sort-of-catalyst, that ended up contaminating the drained off glycerine, and was not present in the product. Though I note that ethanol can be used in place of it - with much nastier process control and conditions though. May be a bonus in some outlets if it is metabolised ![]() Excess methanol ends up in the glycerin, along with traces of soap, and the sodium ends up down there too but I don't know in what form (perhaps as soap.) The process uses excess alcohol to encourage it to go to completion. Large processors recover the waste methanol; it's easier to distill out than is ethanol. The chemicals in methyl ester biodiesel are considered safe by the FDA, and I believe they have some use as food additives. Tests with rats show that methyl biodiesel is nontoxic. That doesn't mean it's good for cooking, but you are unlikely to poison yourself. Bob |
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